[057] Ginzburg-Landau theory of the liquid-solid interface and nucleation for hard spheres
The Ginzburg-Landau free energy functional for hard spheres is constructed using the fundamental measure theory approach to density functional theory as a starting point. The functional is used to study the liquid-fcc solid planer interface and the properties of small solid clusters nucleating within a liquid. The surface tension for planer interfaces agrees well with simulation and it is found that the properties of the solid clusters are consistent with classical nucleation theory.
Recommended citation: James F. Lutsko, "Ginzburg-Landau theory of the liquid-solid interface and nucleation for hard spheres", Phys. Rev. E, 74, 21603 (2006)
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